Synthesis, Crystal Structure and Magnetic Properties of a Novel (GdIII-CuII) Heterodinuclear Complex
نویسندگان
چکیده
منابع مشابه
Synthesis, Crystal Structure and Magnetic Properties of a Novel Gdm-Cun Heterodinuclear Complex
Z. Naturforsch. 55 b, 1131-1136 (2000); received July 24, 2000 Heterodinuclear Complex, Super-Exchange Interactions, Lanthanides Preparation, crystal structure and magnetic properties of a heterodinuclear complex, LCu(Me2C0 )Gd(N03)3 (L = (N,N'-bis(3-methoxysalicylidene)propane1,2-diamine) are re ported. The crystal structure of the complex was determined by X-ray diffraction methods at 200 K....
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The crystal structure of L’Cu(Me2CO)Nd(NO3)3 (L’ = N,N’-bis(2-hydroxy-3-methoxybenzylidene)-ethylenediamine) was determined and the magnetic properties of the complex were investigated. (C18H18N2O4)Cu(C3H6O)Nd(NO3)3, monoclinic, space group P21/c, with a = 9.8792(9), b = 18.904(4), c = 15.667(2) Å, β = 95.360(10)◦ , V = 2913.1(8) Å3, Z = 4. The central region of the complex is occupied by CuII ...
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The crystal structure and the magnetic properties of a heterodinuclear complex, [LCu(Me2CO)Gd(NO3)3]2 (L=N,N’-bis(2-hydroxy-3-methoxybenzylidene)-1,3-diaminopropane) are reported: [(C19H20N2O4)Cu(C3H6O)Gd(NO3)3]2, triclinic, space group P1, with a = 12.118.3(9), b = 13.562(3), c = 9.391(3) Å, α = 93.03(3), β = 107.65(2), γ = 73.07(2)◦ , V = 1406.0(7) Å3, Z = 1. The crystal structure consists of...
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The reaction of gallium (III) nitrate octahydrate with the proton transfer compound (pydaH2)2+ (pydc)2– ( where pyda is 2,6-pyridinediamine and pydcH2 is 2,6-pyridinedicarboxylic acid) leads to the formation of (C5H8N3) [Ga(C7H3NO4)2] · 4H2O · CH3OH. The crystal system of the anionic complex is triclinic with space group Pī and two molecules per unit cell. The unit cell parameters are a=10.23...
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The synthesis, crystal structure and magnetic properties of [Mn(III)L(H2O)2]+ClO4−, 1 [L = N,N′-bis(rac-3,5-dichlorosalicylidenato)-1,2-diaminopropane] are reported. Single crystal X-ray diffraction studies showed the structure to consist of [MnL(H2O)2] octahedra, with trans-coordinated water molecules, which are linked into infinite helices by hydrogen bonds. The distorted octahedral manganese...
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ژورنال
عنوان ژورنال: Acta Crystallographica Section A Foundations of Crystallography
سال: 2000
ISSN: 0108-7673
DOI: 10.1107/s0108767300027124